Here was one of many references to DIY octane booster:
http://swimminginthought.com/boosting-octane-yourself-research-it-proved-it/ Here's another that breaks down common off-the-shelf octane boosters:
http://www.hotrodders.com/forum/octane-booster-info-124750.html. What you'll notice is that in a number of the products the main component is kerosene (effectively diesel/Jet A). In the homebrew recipe, the major component is toluene or xylenes. I also read that toluene is already a sizable component in premium gasoline. Also take note that these users are running race engines and other high-performance applications. One TouTube video has a guy putting half-a-gallon of straight xylenes into 3/4 tank of regular gas in his 550S Benz. He states that he's been doing that to his $110K car for 17K miles (since new). There are other examples.
To me, it seems that regular gas (octane 87) has an advanced ignition more than premium (octane 91) and premium more advanced than diesel/kerosene/Jet A. To get rid of pre-deonation, it makes sense that compounds that retard ignition would get rid of pre-detonation. Here's a decent treatise on the subject:
http://en.wikipedia.org/wiki/Engine_knocking This article also speaks to the evil knocking does to the engine. That has me scared to death.
Watcher, thanks for the offer to send me a tune or two. I now have an email entered in my profile. Let me know if it works.